Product ID:42844 VOC-1, 3.2ML VOLATILE ORGANIC CONTAMINANTS MIX 1
MSDS Date:12/03/1991
FSC:6810
NIIN:00F026465
MSDS Number: BQJHF

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

BROMOBENZENE

CAS: 108-86-1

RTECS: CY9000000

Fraction By Weight: 0.005%

DIBROMOMETHANE

CAS: 74-95-3

RTECS: PA7350000

Fraction By Weight: 0.005%

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-CHLOROTOLUENE

CAS: 106-43-4

RTECS: XS9010000

Fraction By Weight: 0.005%

1,1-DICHLOROPROPYLENE

CAS: 563-58-6

RTECS: UC8290000

Fraction By Weight: 0.005%

PROPANE, 2,2-DICHLORO- 2,2-DICHLOROPROPANE

CAS: 594-20-7

Fraction By Weight: 0.005%

METHANOL (METHYL ALCOHOL), COLUMBIAN SPIRITS

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 99-100%

OSHA PEL S,200PPM/250STEL

ACGIH TLV: S,200PPM/250STEL; 93

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

DIBROMOETHANE, ETHYLENE DIBROMIDE, 1,2-DIBROMOETHANE

CAS: 106-93-4

RTECS: KH9275000

Fraction By Weight: 0.005%

OSHA PEL 200 PPM

ACGIH TLV: A2 CARCINOGEN

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2-DIBROMO-3-CHLOROPROPANE (DBCP)

CAS: 96-12-8

RTECS: TX8750000

Fraction By Weight: 0.005%

OSHA PEL 0.001 PPM CANCER HAZ

ACGIH TLV: NONE

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

STYRENE, (MONOMER), SUSPECTED ANIMAL CARCINOGEN BY IARC &

CAS: 100-42-5

RTECS: WL3675000

Fraction By Weight: 0.005%

OSHA PEL 100 PPM

ACGIH TLV: S,50PPM/100STEL;9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

P-XYLENE

CAS: 106-42-3

RTECS: ZE2625000

Fraction By Weight: 0.005%

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LD50 LC50 Mixture:LD50 ORAL (RAT): 5628 MG/KG METHANOL
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALATION: HARMFUL, HEADACHE, NAUSEA
& GASTROINTESTINAL DISTURBANCES. INGESTION: FATAL, BLINDNESS.
Explanation of Carcinogenicity:SEE INGREDIENTS
Effects of Overexposure:INGESTION: MAY CAUSE CANCER.

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS. SKIN: WASH W/LARGE
AMOUNTS OF WATER. INHALATION: REMOVE TO FRESH AIR. IF BREATHING
STOPS, GIVE ARTIFICIAL RESPIRATION. INGESTION: NEVER GIVE ANYTHING
BY MOUTH TO AN UNCONSCIOUS PERSON. NEVER TRY TOMAKE AN UNCONSCIOUS
PERSON VOMIT. GIVE 2 TABLESPOONS OF BAKING SODA IN A GLASS OF
WATER, PRESS FINGERS BACK OF TONGUE TO INDUCE VOMIT. OBTAIN MEDICAL
ATTENTION.

Flash Point:50F
Lower Limits:6.0%
Upper Limits:36.5%
Extinguishing Media:CO2, DRY CHEMICAL, ALCOHOL FOAM
Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS WHEN
FIGHTING A CHEMICAL FIRE.
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION. HYDROCHLORIC ACID,
HYDROGEN BROMIDE.

Spill Release Procedures:TAKE UP W ABSORBENT MATERIAL. VENTILATE AREA.
ELIMINATE ALL IGNITION SOURCES.

Handling and Storage Precautions:STORE IN SEALED CONTAINERS IN COOL,
DRY LOCATION. KEEP AWAY FROM OXIDIZERS. KEEP AWAY FROM IGNITION
SOURCES.
Other Precautions:AVOID EYE/SKIN CONTACT. AVOID BREATHING VAPORS.

Respiratory Protection:WEAR FACE MASK W/ORGANIC VAPOR CANISTER.
Ventilation:ADEQUATE
Protective Gloves:RUBBER
Eye Protection:PROTECTIVE GLASSES
Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHES BEFORE
REUSE. WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
PRODUCT SHOULD BE HANDLED ONLY BY QUALIFIED PERSONS TRAINED IN
LABORATORY PROCEDURES & GOOD SAFETY PRACTICES.

Boiling Pt:B.P. Text:65C
Melt/Freeze Pt:M.P/F.P Text:-98C
Vapor Pres:100
Vapor Density:1.1
Spec Gravity:0.79
Evaporation Rate & Reference:(ETHER = 1) >1
Solubility in Water:COMPLETE
Appearance and Odor:CLEAR COLORLESS LIQUID
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
OXIDIZING AGENTS, CHROMIC ANHYDRIDE, LEAD PERCHLORATE, PERCHLORIC
ACIDS.
Stability Condition to Avoid:ALL IGNITION SOURCES.
Hazardous Decomposition Products:HYDROCHLORIC ACID, HYDROGEN BROMIDE

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/FEDERAL, STATE &
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.